Villarreal midfielder Pablo Fornals had to be taken to hospital after fainting during training and will miss Sunday's LaLiga game against Barcelona as a result.
Fornals made an "immediate recovery" but remains under observation in hospital, it was confirmed by the club on Saturday.
The 21-year-old, who has started 13 league games this season after joining the club from Malaga in July, is reported to have been suffering from low blood sugar.
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Denis Cheryshev and Nicola Sansone are also unavailable for the game against the league leaders, while Andres Fernandez remains out with a knee injury.
However, coach Javi Calleja is expected to welcome back goalkeeper Sergio Asenjo - who has not played a league game since February due to an anterior cruciate ligament injury - while Samu Castillejo and Ruben Semedo have also returned to the squad.
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